Next time you want to introduce someone to Star Wars for the first time, watch the films with them in this order: IV, V, II, III, VI
As I mentioned, this creates a lot of tension after the cliffhanger ending of Episode V. It also uses the original trilogy as a framing device for the prequel trilogy. Vader drops this huge bomb that he's Luke's father, then we spend two movies proving he's telling the truth, then we see how it gets resolved. The Star Wars watching experience gets to start with the film that does the best job of establishing the Star Wars universe, Episode IV, and it ends with the most satisfying ending, Episode VI. It also starts the series off with the two strongest films, and allows you to never have to either start or end your viewing experience with a shitty movie. Two films of Luke's story, two films of Anakin's story, then a single film that intertwines and ends both stories.